Avoiding malnutrition/vitamin deficiency with supplements

Are supplements (like Centrum) enough to avoid vitamin deficiency? Let's say you're stuck someplace where you're limited to one or two types of bulk foods, like rice or bread. Obviously that alone will only provide calories (you'll get vitamin deficiency regardless of how much you eat and die). Will pill supplements allow a person to avoid this?

Alternatively, if you could replace rice with one or two foods, what would they be to maximize survival chances?

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Avoiding malnutrition/vitamin deficiency with supplements